Disc 1 : 1981-1983

   1. "I Don't Know (Live)" (Ozzy Osbourne, Randy Rhoads, Bob Daisley) – 5:02
          * From Tribute
   2. "Mr. Crowley" (Ozzy Osbourne, Randy Rhoads, Bob Daisley) – 4:56
          * From Blizzard of Ozz
   3. "Crazy Train" (Osbourne, Rhoads, Daisley) – 4:49
          * From Blizzard of Ozz
   4. "Goodbye to Romance (Live)" (Osbourne, Rhoads, Daisley) – 5:24
          * From Randy Rhoads Tribute
   5. "Suicide Solution (Live)" (Osbourne, Rhoads, Daisley) – 7:58
          * From Tribute
   6. "Over the Mountain" (Osbourne, Rhoads, Daisley, Lee Kerslake) – 4:32
          * From Diary of a Madman
   7. "Flying High Again (Live)" (Osbourne, Rhoads, Daisley, Kerslake) – 4:26
          * From Tribute
   8. "You Can't Kill Rock and Roll" (Osbourne, Rhoads, Daisley, Kerslake) – 6:43
          * From Diary of a Madman
   9. "Diary of a Madman" (Osbourne, Rhoads, Daisley, Kerslake) – 6:13
          * From Diary of a Madman
  10. "Bark at the Moon" (Osbourne) – 4:23
          * From B-Side of So Tired
  11. "Spiders in the Night" (Osbourne) – 4:28
          * From Bark at the Moon
  12. "Rock 'n' Roll Rebel" (Osbourne) – 5:22
          * From Bark at the Moon
  13. "You're No Different" (Osbourne) – 5:49
          * From Bark at the Moon

Disc 2 : 1986-2001

  14. "The Ultimate Sin (Live)" (Osbourne, Jake E. Lee, Daisley) – 4:43
          * From The Ultimate Ozzy video
  15. "Never Know Why (Live)" (Osbourne, Lee, Daisley) – 4:43
          * From The Ultimate Ozzy video
  16. "Thank God for the Bomb (Live)" (Osbourne, Lee, Daisley) – 4:00
          * From The Ultimate Ozzy video
  17. "Crazy Babies" (Osbourne, Zakk Wylde, Daisley, Randy Castillo) – 4:15
          * From No Rest for the Wicked
  18. "Breakin' All the Rules" (Osbourne, Wylde, Daisley, Castillo, John Sinclair) – 5:12
          * From No Rest for the Wicked
  19. "I Don't Want to Change the World (Demo)" (Osbourne, Wylde, Castillo, Lemmy) – 3:56
          * From The No More Tears Demo Sessions
  20. "Mama, I'm Coming Home (Demo)" (Osbourne, Wylde, Lemmy) – 4:08
          * From The No More Tears Demo Sessions
  21. "Desire (Demo)" (Osbourne, Wylde, Castillo, Lemmy) – 5:01
          * From The No More Tears Demo Sessions
  22. "No More Tears" (Osbourne, Wylde, Mike Inez, Castillo, John Purdell) – 7:23
          * From No More Tears
  23. "Won't Be Coming Home (S.I.N.) (Demo)" (Osbourne, Wylde, Castillo) – 4:59
          * From The No More Tears Demo Sessions
  24. "Perry Mason (Live)" (Osbourne, Wylde, Purdell) – 5:56
          * From Ozzfest 1
  25. "See You on the Other Side (Demo)" (Osbourne, Wylde, Lemmy) – 6:34
          * Unreleased demo recorded during the No More Tears tour
  26. "Walk on Water (Demo)" (Osbourne, Jim Vallance) – 4:41
          * From Beavis and Butt-head Do America
  27. "Gets Me Through (Live)" (Osbourne, Tim Palmer) – 4:28
          * From Live at Budokan
  28. "Bang Bang (You're Dead)" (Osbourne, Palmer, Scott Humphrey, Geoff Nicholls) – 4:33
          * Early version of "Facing Hell" from the Down to Earth sessions.
  29. "Dreamer" (Osbourne, Marti Frederiksen, Mick Jones) – 4:45
          * From Down to Earth

Disc 3 : With Friends

  30. "Iron Man" (Osbourne, Tony Iommi, Geezer Butler, Bill Ward) – 5:26
          * Ozzy Osbourne with Therapy?
          * From 1994 in Nativity in Black tribute
  31. "N.I.B." (Osbourne, Iommi, Butler, Ward) – 5:58
          * Ozzy Osbourne with Primus
          * From 1999-2000 in Nativity in Black II tribute
  32. "Purple Haze" (Jimi Hendrix) – 4:22
          * From 1989 in Stairway to Heaven/Highway to Hell compilation
  33. "Pictures of Matchstick Men" (Francis Rossi) – 6:02
          * Ozzy Osbourne with Type O Negative
          * From 1997 in Howard Stern - Private Parts OST
  34. "Shake Your Head (Let's Go To Bed)" (Don Was, David Was, Jarvis Stroud) – 3:55
          * Ozzy Osbourne with Was (Not Was)
          * From 1982-83 in Born to Laugh at Tornadoes album of Was (Not Was)
  35. "Born to Be Wild" (Mars Bonfire) – 3:29
          * Ozzy Osbourne with Miss Piggy
          * From 1994 in Kermit Unpigged compilation
  36. "Nowhere to Run (Vapor Trail)" (Osbourne, Earl Simmons, Jack Blades, John Eaton, Ken Jordan, Russell Jones, Rick Rubin, Scott Kirkland) – 4:44
          * Ozzy Osbourne with The Crystal Method, DMX, Ol' Dirty Bastard & Fuzzbubble
          * From 1998 in Chef Aid: The South Park Album OST
  37. "Psycho Man" (Osbourne, Iommi) – 5:18
          * Black Sabbath
          * From 1998 in Reunion
  38. "For Heaven's Sake 2000" (Osbourne, Iommi, Bob Marlette, Darryl Hill, Elgin Turner, Jason Hunter, Robert Diggs) – 4:57
          * Ozzy Osbourne with Tony Iommi and Wu-Tang Clan
          * From 1999 in Loud Rocks compilation
  39. "I Ain't No Nice Guy" (Lemmy) – 4:15
          * Ozzy Osbourne with Motörhead and Slash
          * From 1992 in March ör Die
  40. "Therapy" (Mike Muir, Robert Trujillo) – 3:25
          * Ozzy Osbourne with Infectious Grooves
          * From 1991 in The Plague That Makes Your Booty Move...It's the Infectious Grooves
  41. "Stayin' Alive" (Barry Gibb, Robin Gibb, Maurice Gibb) – 4:39
          * Ozzy Osbourne with Dweezil Zappa
  42. "Dog, The Bounty Hunter" (Osbourne, Mark Hudson) – 0:53

Disc 4 : Under Covers

  43. "21st Century Schizoid Man" (Robert Fripp, Michael Giles, Greg Lake, Ian McDonald, Peter Sinfield) – 3:52
          * King Crimson cover
  44. "Mississippi Queen" (Wes Golding) – 4:09
          * Mountain cover
  45. "All The Young Dudes" (David Bowie) – 4:36
          * Mott the Hoople cover
  46. "In My Life" (John Lennon, Paul McCartney) – 3:29
          * The Beatles cover
  47. "Fire" (Arthur Brown, Vincent Crane, Mike Finesilver, Peter Ker) – 4:09
          * Crazy World of Arthur Brown cover
  48. "For What It's Worth" (Stephen Stills) – 3:20
          * Buffalo Springfield cover
  49. "Sympathy for the Devil" (Mick Jagger, Keith Richards) – 7:12
          * The Rolling Stones cover
  50. "Working Class Hero" (Lennon) – (3:24)
          * John Lennon cover
  51. "Good Times" (Barry Jenkins, Daniel McCulloch, Eric Burdon, John Weider, Vic Briggs) – 3:46
          * Eric Burdon & The Animals cover
  52. "Changes" (Osbourne, Iommi, Butler, Ward, Kelly Osbourne) – 4:06
          * Ozzy Osbourne with Kelly Osbourne